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Sakiko Kasuya, Yukika Yamazawa, Natsuhiko Sugimura, Toshimichi Shibue, Teruyuki Komatsu, Fluorescent Dimer and Fiber of meso-Tetrakis{o-(isonicotinoylamino)phenyl}porphyrin Connected by Pd(II) Coordinations, Chemistry Letters, Volume 43, Issue 7, July 2014, Pages 1008–1010, https://doi.org/10.1246/cl.140243
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Abstract
A pair of meso-tetrakis{α,α,α,α-o-(isonicotinoylamino)phenyl}porphyrins (P1) was coupled by quadruple Pd(II) coordinations, generating a cofacial and fluorescent porphyrin dimer. Photoinduced electron transfers from the dimer to benzoquinones were investigated. Furthermore, Pd(II) coordinations to the α,β,α,β-atropisomer P2 yielded fluorescent porphyrin fiber with a monomolecular width.
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